Catalysis Communications ( IF 3.7 ) Pub Date : 2018-04-12 , DOI: 10.1016/j.catcom.2018.04.011 Tao Li , Deping Xia , Guilin Zhou , Hongmei Xie , Zhaojie Jiao , Xianming Zhang
CeO2 nanorods and nanocubes, which were used as supports to Pd (3.0 wt.%)/CeO2 catalysts, which were prepared by hydrothermal method. TEM, HRTEM, XRD, and H2-TPD were used to study the physic-chemical properties of the Pd/CeO2 catalysts. The Pd/CeO2 catalysts were applied to investigate the vapor phase benzene catalytic hydrogenation reaction under atmospheric pressure at the temperature of 100–200 °C. Results show that the Pd/CeO2 catalysts exhibit morphology-dependent catalytic activity. The Pd/CeO2 nanorod catalyst (PC100) has a superior vapor phase benzene catalytic hydrogenation performance. The benzene catalytic hydrogenation conversion and cyclohexane selectivity are 96.4% and 100% at 200 °C, respectively.
中文翻译:
形态对Pd / CeO 2催化剂上气相苯催化加氢的影响
CeO 2纳米棒和纳米立方体用作水热法制备的Pd(3.0 wt%)/ CeO 2催化剂的载体。TEM,HRTEM,XRD和H 2 -TPD用于研究Pd / CeO 2催化剂的物理化学性质。利用Pd / CeO 2催化剂研究了在大气压下于100–200°C的温度下气相苯催化的加氢反应。结果表明,Pd / CeO 2催化剂表现出形态依赖性的催化活性。Pd / CeO 2纳米棒催化剂(PC100)具有优异的气相苯催化加氢性能。苯催化加氢转化率和在200°C下的环己烷选择性分别为96.4%和100%。