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Mechanochemistry breaks with expectations
Nature Catalysis ( IF 37.8 ) Pub Date : 2018-04-16 , DOI: 10.1038/s41929-018-0061-1
Jörg Weissmüller

Mechanochemistry breaks with expectations

Mechanochemistry breaks with expectations, Published online: 16 April 2018; doi:10.1038/s41929-018-0061-1

Tensile strain of a solid surface can result in either strengthening or weakening of bonds with adsorbates. Adsorption energies of different adsorbate/site combinations may be shifted in different directions — a striking violation of the Brønsted–Evans–Polanyi relation.


中文翻译:

机械化学打破了预期

机械化学打破了预期

机械化学打破了预期,在线发布:2018年4月16日; doi:10.1038 / s41929-018-0061-1

固体表面的拉伸应变会导致与被吸附物之间的键增强或减弱。不同吸附物/位点组合的吸附能可能会朝不同的方向移动,这明显违反了Brønsted–Evans–Polanyi关系。
更新日期:2018-04-16
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