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Hydrogen-bond-linked photocatalyst of g-C3N4/3, 4, 9, 10-perylenetetracarboxylic acid anhydride with different bay-substitutents
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-04-11
Shuo Zhang, Huiyun Guo, Qizhe Li, Lan Yu, Haiquan Zhang

To form stable the graphitic carbon nitride (g-C3N4) composite photocatalyst with high repeatability, the hydrogen bonding composite was facilely built by g-C3N4 with two perylene anhydride derivatives (3,4,9,10-perylenetetracarboxylic acid anhydride (PTCDA) and 1,6,7,12-tetrachloroperylene-3,4,9,10- tetracarboxylic acid (TClPTCDA)). Intermolecular hydrogen bond was confirmed by analysis of FT-IR, XPS and DSC data. In contrast with their raw materials, the composite photocatalysts would significantly improve the photocatalytic activity to rhodamine B under visible light radiation. Furthermore, the TClPTCDA/g-C3N4 (TClP-g) prossesses higher photocatalytic activity than that of PTCDA/g-C3N4 (P-g) under same experimental condition.



中文翻译:

gC 3 N 4 / 3、4、9、10 -per四羧酸酐具有不同海湾取代基的氢键键合光催化剂

为了形成稳定的,具有高重复性的石墨氮化碳(gC 3 N 4)复合光催化剂,通过gC 3 N 4与两种per酸酐衍生物(3,4,9,10-tetra四羧酸酐(PTCDA) )和1,6,7,12-四氯per-3,4,9,10-四羧酸(TC1PTCDA))。通过FT-IR,XPS和DSC数据的分析证实了分子间氢键。与它们的原料相比,复合光催化剂将在可见光辐射下显着提高对若丹明B的光催化活性。此外,TClPTCDA / gC 3 N 4在相同的实验条件下(TClP-g)具有比PTCDA / gC 3 N 4(Pg)更高的光催化活性。

更新日期:2018-04-12
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