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Convergent Synthesis of Novel Mono- and Di-substituted 1,2-Isopropylideneglucofuranose Appended Dendrimers with a Ferrocene Core and their Electrochemical Studies
Synlett ( IF 2 ) Pub Date : 2018-04-10 , DOI: 10.1055/s-0037-1609490
Ankur Ray 1 , Sabiha Khan 2
Affiliation  

Ferrocene-cored dendrimers incorporating 1,2-isopropylidenefuranose capped furanoside branches were synthesized and their electrochemical properties were studied. It was observed that the dendritic environment in the ferrocene dendrimers increased the E 1/2 values with increase in bulk of the dendrimer, as expected. The reversible nature of the redox process was maintained in all the dendrimers.

中文翻译:

具有二茂铁核的新型单和二取代 1,2-异亚丙基葡萄糖呋喃糖附加树枝状聚合物的聚合合成及其电化学研究

合成了包含 1,2-异亚丙基呋喃糖封端的呋喃糖苷支链的二茂铁核树枝状聚合物,并研究了它们的电化学性能。正如预期的那样,观察到二茂铁树枝状聚合物中的树枝状环境随着树枝状聚合物体积的增加而增加了 E 1/2 值。在所有树枝状聚合物中都保持了氧化还原过程的可逆性质。
更新日期:2018-04-10
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