Cloud/aerosol water surfaces exert significant influence over atmospheric chemical processes. Atmospheric processes at the water surface are observed to follow mechanisms that are quite different from those in the gas phase. This Account summarizes our recent findings of new reaction pathways on the water surface. We have studied these surface reactions using Born–Oppenheimer molecular dynamics simulations. These studies provide useful information on the reaction time scale, the underlying mechanism of surface reactions, and the dynamic behavior of the product formed on the aqueous surface.

中文翻译：

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洞察云/气溶胶水表面的化学

云/气溶胶水面对大气化学过程产生重大影响。观察到水表面的大气过程遵循与气相完全不同的机理。本报告总结了我们最近在水表面上新反应途径的发现。我们已经使用Born-Oppenheimer分子动力学模拟研究了这些表面反应。这些研究提供了有关反应时间尺度，表面反应的潜在机理以及在水表面形成的产物的动力学行为的有用信息。