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Microspherical MnO2-CeO2-Al2O3 mixed oxide for monolithic honeycomb catalyst and application in selective catalytic reduction of NOx with NH3 at 50-150 °C
Chemical Engineering Journal ( IF 15.1 ) Pub Date : 2018-04-07
Chao Wang, Feng Yu, Mingyuan Zhu, Xugen Wang, Jianming Dan, Jinli Zhang, Peng Cao, Bin Dai

MnOx-CeO2-Al2O3 microspheres (MSs) were successfully designed and synthesized via spray drying (SD) and easily used for monolithic honeycomb catalyst (MHC). The as-obtained MnOx-CeO2-Al2O3 (SD) catalyst exhibited a great BET surface area of 201.4 m2/g, a pore volume of 0.29 cm3/g, and an average pore diameter of 5.8 nm. Furthermore, the MnOx-CeO2-Al2O3 (SD) MSs delivered much more Olatt sits resulting in enhanced catalytic activity at low temperature. The MnOx-CeO2-Al2O3 (SD) performed excellent NOx conversion of 97.4% and N2 selectivity of 94.5% at 150 °C with a gas hourly space velocity (GHSV) of 15000 h-1, and NOx concentration of 500 ppm. Even at 50 °C and 100 °C, the titled product still exhibited great N2 selectivity of 95.5% and 96.1%, respectively, corresponding to the NOx conversion of 55% and 98.0%, respectively. The MnOx-CeO2-Al2O3 (SD) monolithic honeycomb catalyst (MHC) was prepared by vacuum-impregnation method. The MnOx-CeO2-Al2O3 (SD-MHC) delivered NOx conversion of 93% at 150 °C with a GHSV of 2000 h-1, and NOx concentration of 500 ppm. Even at 50 °C and 100 °C, the titled product still performed NOx conversion of 55% and 83%, respectively. The MnOx-CeO2-Al2O3 (MHC) performed great catalytic activity in the low temperature arrange from 50 to 150 °C and presented potential application in stationary industrial installations.



中文翻译:

微珠的MnO 2 -CeO 2 -Al 2 ö 3 混合在选择性催化还原NO的单块蜂窝体催化剂和应用氧化物X 与NH 3在50-150℃下

通过喷雾干燥(SD)成功设计合成了MnO x -CeO 2 -Al 2 O 3微球(MSs),易于用于整体式蜂窝催化剂(MHC)。所获得的MnO x -CeO 2 -Al 2 O 3(SD)催化剂显示出大BET表面积为201.4m 2 / g,孔体积为0.29cm 3 / g,平均孔径为5.8nm。此外,MnO x -CeO 2 -Al 2 O 3(SD)MS传递的油量更多导致低温下催化活性增强。MnO的X -CeO 2 -Al 2 ö 3(SD)执行优良NO X的97.4%的转化率和N 2的选择性在150℃下为94.5%与气时空速15000 H(GHSV)-1,和NO x浓度为500 ppm。即使在50℃和100℃下,标题产物仍显示出分别为95.5%和96.1%的高N 2选择性,对应于分别为55%和98.0%的NO x转化率。MnO x -CeO 2 -Al 2 O 3(SD)整体式蜂窝催化剂(MHC)是通过真空浸渍法制备的。MnO的X -CeO 2 -Al 2 ö 3(SD-MHC)递送NO X的93%的转化率在150℃下以2000小时GHSV -1,和NO X为500ppm的浓度。甚至在50℃和100℃,标题产物仍然没有进行X分别为55%和83%的转化率。MnO x -CeO 2 -Al 2 O 3(MHC)在50至150°C的低温下表现出出色的催化活性,并在固定工业装置中具有潜在的应用前景。

更新日期:2018-04-07
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