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Formamidinium Lead Bromide (FAPbBr3) Perovskite Microcrystals for Sensitive and Fast Photodetectors
Nano-Micro Letters ( IF 26.6 ) Pub Date : 2018-04-02 , DOI: 10.1007/s40820-018-0196-2
Fengying Zhang , Bin Yang , Kaibo Zheng , Songqiu Yang , Yajuan Li , Weiqiao Deng , Rongxing He

Because of the good thermal stability and superior carrier transport characteristics of formamidinium lead trihalide perovskite HC(NH2)2PbX3 (FAPbX3), it has been considered to be a better optoelectronic material than conventional CH3NH3PbX3 (MAPbX3). Herein, we fabricated a FAPbBr3 microcrystal-based photodetector that exhibited a good responsivity of 4000 A W−1 and external quantum efficiency up to 106% under one-photon excitation, corresponding to the detectivity greater than 1014 Jones. The responsivity is two orders of magnitude higher than that of previously reported formamidinium perovskite photodetectors. Furthermore, the FAPbBr3 photodetector’s responsivity to two-photon absorption with an 800-nm excitation source can reach 0.07 A W−1, which is four orders of magnitude higher than that of its MAPbBr3 counterparts. The response time of this photodetector is less than 1 ms. This study provides solid evidence that FAPbBr3 can be an excellent candidate for highly sensitive and fast photodetectors.
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中文翻译:

甲ami溴化铅(FAPbBr3钙钛矿微晶,用于灵敏和快速的光电探测器

由于甲ami鎓三卤化钙钛矿HC(NH 22 PbX 3(FAPbX 3)的良好的热稳定性和优异的载流子传输特性,它被认为是比常规CH 3 NH 3 PbX 3(MAPbX 3)更好的光电材料。)。本文中,我们制造了一种基于FAPbBr 3微晶的光电探测器,该探测器在单光子激发下具有4000 A W -1的良好响应度和高达10 6%的外部量子效率,对应于大于10 14的探测率琼斯 响应度比以前报道的甲ami钙钛矿光电探测器高两个数量级。此外,FAPbBr 3光电探测器对800 nm激发源对双光子吸收的响应度可以达到0.07 A W -1,比其MAPbBr 3对应物高出四个数量级。该光电探测器的响应时间小于1毫秒。这项研究提供了有力的证据,表明FAPbBr 3可以成为高灵敏度和快速光电探测器的绝佳候选者。
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更新日期:2018-04-02
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