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A W-Shaped Ga-Dy-Dy-Dy-Ga Cluster: Synthesis, Characterization, and Magnetic Properties.
ChemPlusChem ( IF 3.4 ) Pub Date : 2018-05-08 , DOI: 10.1002/cplu.201800049
Yan Peng 1, 2 , Christopher E Anson 1 , Annie K Powell 1, 2
Affiliation  

A W-shaped {Ga-Dy-Dy-Dy-Ga} coordination cluster, [Ga2 Dy3 (L)6 (MeO)2 (MeOH)3 ]⋅NO3 ⋅7 MeOH (1) with H2 L, (E)-2-(2-hydroxy-3-methoxy-benzylideneamino)phenol was synthesized, characterized, and the magnetic properties investigated. The magnetic measurements indicate that the compound shows single-molecule magnet (SMM) behavior under zero dc field. This suggests that the combination of GaIII ions and DyIII ions (4 f) is a successful strategy to assemble SMM clusters. The combination of these metal ions also offers prospects in dual functionality therapeutics for medical applications.

中文翻译:

W形的Ga-Dy-Dy-Dy-Ga团簇:合成,表征和磁性能。

W形{Ga-Dy-Dy-Dy-Ga}配位簇[Ga2 Dy3(L)6(MeO)2(MeOH)3]·NO3·7 MeOH(1)和H2 L,(E)-合成了2-(2-羟基-3-甲氧基-亚苄基氨基)苯酚,进行了表征,并研究了磁性。磁测量表明该化合物在零直流磁场下表现出单分子磁体(SMM)行为。这表明GaIII离子和DyIII离子(4 f)的组合是组装SMM簇的成功策略。这些金属离子的组合还为医疗应用的双功能疗法提供了前景。
更新日期:2018-05-08
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