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Unified theoretical treatment of the Eirrev, CE, EC and CEC mechanisms under voltammetric conditions
Electrochemistry Communications ( IF 5.4 ) Pub Date : 2018-04-03 , DOI: 10.1016/j.elecom.2018.03.011
A. Molina , M. López-Tenés , E. Laborda

Via a thoughtful analysis it is demonstrated that the mathematical problem of the voltammetry of a simple charge transfer process of any reversibility degree at a macrointerface is totally equivalent to those of the CE, EC and CEC mechanisms such that they all can be reduced to a formally identical one-variable problem. The simplicity and generality of the resulting boundary value problem makes it very easy and rapid the study of the response in any voltammetric technique by analytical or numerical methods.



中文翻译:

伏安条件下E irrev,CE,EC和CEC机制的统一理论处理

通过深思熟虑的分析,证明了在宏接口上具有任何可逆性的简单电荷转移过程的伏安法的数学问题完全等同于CE,EC和CEC机制的问题,因此它们都可以形式化地简化。相同的一变量问题。所产生的边值问题的简单性和普遍性使得通过分析或数值方法在任何伏安技术中研究响应变得非常容易和迅速。

更新日期:2018-04-03
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