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Reaction-based AIEE-active conjugated polymer as fluorescent turn on probe for mercury ions with good sensing performance
Dyes and Pigments ( IF 4.5 ) Pub Date : 2018-03-30 , DOI: 10.1016/j.dyepig.2018.03.060
Yuanrong Shan , Wenjie Yao , Ziqin Liang , Lihong Zhu , Shuibin Yang , Zhijun Ruan

Based on Hg2+-promoted deprotection reaction of thioketal, a type of thioketal decorated conjugated polymer (PTS) with the feature of aggregation induced emission enhancement (AIEE) was successfully synthesized as fluorescent turn on probe for Hg2+. With the introduction of trace aqueous Hg2+, fluorescence of PTS in THF-H2O mixture (water fraction of 98%) exhibited significant enhancement. The response was very fast with good selectivity towards Hg2+ due to the specific chemical reaction. Other common metal ions (Ag+, Cr3+, Al3+, Fe3+, Ca2+, Ni2+, Co2+, Pb2+, Cu2+, Zn2+, Mg2+, Fe2+, Mn2+, Cd2+, Ba2+, Li+, Na+ and K+) gave nearly no disturbance to the sensing process. Furthermore, the detection limit of Hg2+ reached 2.3 × 10−7 mol L−1 for this sensing system.



中文翻译:

基于反应的AIEE活性共轭聚合物作为荧光开关探针,用于汞离子,具有良好的传感性能

基于Hg 2+促进的硫缩酮的脱保护反应,成功合成了一种具有聚集诱导发射增强(AIEE)特征的硫缩酮修饰的共轭聚合物(PTS)作为Hg 2+的荧光探针。随着痕量Hg 2+水溶液的引入,PTS在THF-H 2 O混合物(水含量为98%)中的荧光显着增强。由于特定的化学反应,反应非常快,对Hg 2+具有良好的选择性。其他常见金属离子(Ag +,Cr 3+,Al 3+,Fe 3+,Ca 2+,Ni 2 +,Co 2 +,Pb 2 +,Cu 2 +,Zn 2 +,Mg 2 +,Fe 2 +,Mn 2 +,Cd 2 +,Ba 2 +,Li +,Na +和K +)几乎没有干扰传感过程。此外,对于该感测系统,Hg 2+的检测极限达到2.3×10 -7  mol L -1

更新日期:2018-03-30
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