当前位置: X-MOL 学术ACS Sustain. Chem. Eng. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Poly(glycerol-co-diacids) Polyesters: From Glycerol Biorefinery to Sustainable Engineering Applications, A Review
ACS Sustainable Chemistry & Engineering ( IF 8.4 ) Pub Date : 2018-03-28 00:00:00 , DOI: 10.1021/acssuschemeng.7b04837
Oscar Valerio 1, 2 , Manjusri Misra 1, 2 , Amar K. Mohanty 1, 2
Affiliation  

Upgrading of biobased glycerol to commercial products is a necessary step on sustainable development of oleaginous biomass biorefining. The synthesis of poly(glycerol-co-diacid) polyester materials is an attractive option for glycerol usage that can produce a wide range of products of commercial interest. These polymeric materials could be used on industrial applications as biomedical devices, surfactants and in thermoplastic material development. In this review, the process engineering aspects leading to tailorable polymeric products are comprehensively analyzed with emphasis on control of molecular architecture and functionality. Molecular weight, degree of branching, mechanical properties and surface chemistry of the materials can be controlled by fine-tuning synthesis procedures to match custom specifications in end products. Potential usage of poly(glycerol-co-diacid) materials with tailored physicochemical properties on industrially relevant applications is presented. Advantages and challenges in the synthesis of these novel polymeric materials for value added application are addressed and discussed.

中文翻译:

聚(甘油-共-二酸)聚酯:从甘油生物炼制厂到可持续工程应用,综述

将生物基甘油升级为商业产品是油质生物质生物精制可持续发展的必要步骤。聚甘油共聚物的合成-二酸)聚酯材料是使用甘油的一种有吸引力的选择,可以生产各种具有商业价值的产品。这些聚合材料可在工业应用中用作生物医学设备,表面活性剂和用于热塑性材料开发。在这篇综述中,对导致可定制的聚合物产品的工艺工程方面进行了全面分析,重点是对分子结构和功能的控制。材料的分子量,支化度,机械性能和表面化学性质可通过微调合成程序来控制,以匹配最终产品中的定制规格。聚甘油共聚物的潜在用途介绍了在工业相关应用中具有特定理化特性的-二酸材料。这些新型聚合物材料在增值应用中的合成优势和挑战得到了解决和讨论。
更新日期:2018-03-28
down
wechat
bug