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Aerosol-assisted deposition of Mn-Fe oxide catalyst on TiO2 for superior selective catalytic reduction of NO with NH3 at low temperatures
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-03-28 , DOI: 10.1016/j.catcom.2018.02.019
Liang-Yi Lin , Chung-Yu Lee , You-Ren Zhang , Hsunling Bai

A series of Me-Fe/TiO2 catalysts was prepared via an aerosol-assisted deposition method, and used for the selective catalytic reduction of NO with NH3 (NH3-SCR) for the first time. Experimental results show that the spray-deposition Mn-Fe/TiO2, denoted Mn-Fe/TiO2(SD), demonstrates high NH3-SCR activity (>95% conversion) with high N2 selectivity (>90%) at temperatures as low as 80–150 °C at a space velocity of 50,000 h−1. Also, the benefits of the spray deposition for preparing Mn-Fe/TiO2 are highlighted by comparison with co-precipitation and wet impregnation. This efficient and reliable technique offers attractive opportunities for large-scale manufacture of promising materials with superior deNOx catalytic performances.



中文翻译:

在TiO 2上气溶胶辅助沉积Mn-Fe氧化物催化剂,以便在低温下以NH 3选择性地催化还原NO

通过气溶胶辅助沉积法制备了一系列Me-Fe / TiO 2催化剂,并首次用于NH 3(NH 3 -SCR)选择性催化还原NO 。实验结果表明,喷涂沉积的Mn-Fe / TiO 2表示为Mn-Fe / TiO 2(SD),显示出高的NH 3 -SCR活性(转化率> 95%)和高的N 2选择性(> 90%)。在50,000 h -1的空速下,温度低至80–150°C 。另外,喷涂沉积对制备Mn-Fe / TiO 2的好处通过与共沉淀和湿法浸渍比较来突出显示。对于具有超强DENO有前途的材料大规模生产这种高效和可靠的技术提供有吸引力的机会X的催化性能。

更新日期:2018-03-28
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