Dyes and Pigments ( IF 4.5 ) Pub Date : 2018-03-27 , DOI: 10.1016/j.dyepig.2018.03.053 R. Vijayakumar , Heng Guo , Xiaoyong Huang
Dy3+ singly doped and Dy3+/Eu3+ co-doped Na3Sc2(PO4)3 phosphors were synthesized by high temperature solid-state reaction and their photoluminescence properties were investigated. The prepared phosphors have a single phase trigonal structure of Na3Sc2(PO4)3 and consist of micro-particles with an average particle size about 13.8 μm. Among all the Na3Sc2(PO4)3:xDy3+ samples, 5 mol% of Dy3+ ions is found to be optimum concentration because it shows strongest emission intensity under 350 nm excitation. Under 350 nm excitation, the emission spectra of Na3Sc2(PO4)3:0.05Dy3+,yEu3+ phosphors are composed of several bands associated with the transitions of both Dy3+ and Eu3+ ions from the 4F9/2 and 5D0 excited states, respectively. It is noticed that integrated emission intensities of Dy3+ ions were decreased with the increase of Eu3+ ion concentration due to energy transfer from Dy3+ to Eu3+ ions. The Dexter theory and Reisfield's approximation were employed to analyze the energy transfer mechanism and it is found that the dipole-dipole interaction is responsible for energy transfer from Dy3+ to Eu3+ ions. Among the Na3Sc2(PO4)3:0.05Dy3+,yEu3+ phosphors, 5 mol% of Dy3+ and 20 mol% of Eu3+ are found to be optimum concentrations because it emits strong warm white light under 350 nm excitation. Further, the quantum efficiency, lifetime, energy transfer efficiency and correlated color temperature (CCT) values of the present phosphors were estimated and compared with the other reported phosphors.
中文翻译:
Dy 3+和Eu 3+共掺杂的Na 3 Sc 2(PO 4)3磷光体的基于近紫外LED的暖白LED的能量转移和颜色可调发光特性
通过高温固相反应合成了Dy 3+单掺杂和Dy 3+ / Eu 3+共掺杂Na 3 Sc 2(PO 4)3荧光粉,并研究了它们的光致发光性能。制备的磷光体具有Na 3 Sc 2(PO 4)3的单相三角结构,并且由平均粒径约为13.8μm的微粒组成。在所有的Na 3 Sc 2(PO 4)3:x Dy 3+样品中,5 mol%的Dy 3+发现离子是最佳浓度,因为它在350 nm激发下显示出最强的发射强度。下350nm处激发,Na组成的发射光谱3钪2(PO 4)3:0.05Dy 3+,YEU 3+磷光体由具有两者的Dy的转变相关联的几个波段的3+及Eu 3+离子从4 F 9/2和5 D 0分别激发态。注意到随着Eu 3+的增加,Dy 3+离子的整体发射强度降低。从Dy 3+到Eu 3+离子的能量转移导致离子浓度升高。用Dexter理论和Reisfield近似法分析了能量转移机理,发现偶极-偶极相互作用是引起Dy 3+到Eu 3+离子能量转移的原因。在Na 3 Sc 2(PO 4)3:0.05Dy 3+,yEu 3+荧光粉中,Dy 3+为5摩尔%,Eu 3+为20摩尔%。被发现是最佳浓度,因为它在350 nm激发下会发出强烈的暖白光。此外,估算了本荧光粉的量子效率,寿命,能量转移效率和相关色温(CCT)值,并将其与其他报道的荧光粉进行了比较。