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Oxidation of a germanium(ii) dication to access cationic germanium(iv) fluorides†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-03-26 00:00:00 , DOI: 10.1039/c8cc01799a Riccardo Suter 1, 2, 3, 4 , Ala'aeddeen Swidan 4, 5, 6, 7 , Charles L. B. Macdonald 4, 5, 6, 7 , Neil Burford 1, 2, 3, 4
Chemical Communications ( IF 4.9 ) Pub Date : 2018-03-26 00:00:00 , DOI: 10.1039/c8cc01799a Riccardo Suter 1, 2, 3, 4 , Ala'aeddeen Swidan 4, 5, 6, 7 , Charles L. B. Macdonald 4, 5, 6, 7 , Neil Burford 1, 2, 3, 4
Affiliation
The synthesis and characterization of the tris(1-ethyl-benzoimidazol-2-ylmethyl)amine (BIMEt3 = L) complex of Ge(II)2+ is described. Oxidation of [LGe]2+ with Selectfluor gives [LGeF2]2+, in a process that is envisaged to involve a tricationic complex [LGeF]3+ as an intermediate, which has been isolated by fluoride ion abstraction from [LGeF2]2+.
中文翻译:
氧化锗(ii)指示剂以获取阳离子锗(iv)氟化物†
描述了Ge(II)2+的三(1-乙基-苯并咪唑-2-基甲基)胺(BIMEt 3 = L)配合物的合成和表征。用Selectfluor氧化[LGe] 2+可以得到[LGeF 2 ] 2+,该过程被认为涉及三阳离子配合物[LGeF] 3+作为中间体,该过程已通过从[LGeF 2 ]中提取氟化物离子而分离出2+。
更新日期:2018-03-26
中文翻译:
氧化锗(ii)指示剂以获取阳离子锗(iv)氟化物†
描述了Ge(II)2+的三(1-乙基-苯并咪唑-2-基甲基)胺(BIMEt 3 = L)配合物的合成和表征。用Selectfluor氧化[LGe] 2+可以得到[LGeF 2 ] 2+,该过程被认为涉及三阳离子配合物[LGeF] 3+作为中间体,该过程已通过从[LGeF 2 ]中提取氟化物离子而分离出2+。