C−N bonds are widely found in natural products, medicinal molecules and multifunctional materials. In recent years, the construction of C−N bonds through a radical coupling reaction between carbon‐centered radicals with nitrogen‐centered radicals has emerged as a frontier area in organic chemistry. This review summarizes the recent advances (especially those after 2012) in radical coupling reactions that facilitate the formation of C−N bonds. The main achievements on this area are presented according to the pattern of the nitrogen‐centered radicals generated. Selected examples of substrates are listed and special attention is paid to the reaction mechanisms. Moreover, a personal outlook is described at the end.

中文翻译：

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通过碳自由基与氮自由基的偶联反应构建C–N键的最新进展

C-N键广泛存在于天然产物，药物分子和多功能材料中。近年来，通过以碳为中心的自由基与以氮为中心的自由基之间的自由基偶联反应来构建C-N键已成为有机化学领域的前沿领域。这篇综述总结了自由基偶联反应的最新进展（尤其是2012年之后的进展），这些进展促进了CN键的形成。根据产生的氮中心自由基的模式，介绍了该领域的主要成就。列出了底物的选定实例，并特别注意了反应机理。此外，最后描述了个人观点。