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Hexaethylbenzene: A Sterically Crowded Arene and Conformationally Versatile Ligand.
ChemPlusChem ( IF 3.4 ) Pub Date : 2018-04-25 , DOI: 10.1002/cplu.201800045
Michael J McGlinchey 1
Affiliation  

The syntheses, structures and dynamic behaviour of hexaethylbenzene and its transition metal and main group element complexes are reviewed. Sterically protected intermediates in the metal-catalysed trimerisation of 3-hexyne to form hexaethylbenzene are described, and the organic chemistry of hexaethylbenzene and of hexamethylbenzene are compared and contrasted.

中文翻译:

六乙苯:拥挤的芳烃和构象多用途的配体。

综述了六乙苯及其过渡金属和主族元素配合物的合成,结构和动力学行为。描述了3-己炔在金属催化的三聚反应中形成六乙基苯的立体保护中间体,并对六乙基苯和六甲基苯的有机化学进行了比较和对比。
更新日期:2018-04-25
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