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A Direct Method to Access Substituted Pyreno[4,5‐c:9,10‐c′] difuran and its Analogues
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2018-04-26 , DOI: 10.1002/ajoc.201800122
Wangqiao Chen 1, 2 , Guankui Long 3 , Koji Kanehira 4 , Mingtao Zhang 3 , Tsuyoshi Michinobu 4 , Ming Liu 2 , Qichun Zhang 1, 5
Affiliation  

In this research, pyreno[4,5‐c:9,10‐c′]difuran and its analogues have been successfully synthesized through a one‐step reaction using the same precursor and their physicochemical properties were studied. UV/Vis, fluorescence and CV measurements illustrated that the inserted chalcogen atoms (O, S and Se) brought almost no change on the photochemical and electrochemical properties whereas TM‐2N‐CH3 exhibited more blue‐shifted fluorescence emission and simultaneously elevated HOMO energy level.

中文翻译:

直接访问取代的Pyreno [4,5-c:9,10-c']二呋喃及其类似物的直接方法

在这项研究中,吡喃并[4,5-c:9,10-c']二呋喃及其类似物已通过一步反应使用相同的前体成功合成,并对其理化性质进行了研究。UV / Vis,荧光和CV测量表明,插入的硫属元素原子(O,S和Se)几乎没有改变光化学和电化学性质,而TM-2N-CH 3表现出更多的蓝移荧光发射,同时HOMO能量升高等级。
更新日期:2018-04-26
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