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In Situ Synthesis of WSe2/CMK-5 Nanocomposite for Rechargeable Lithium-Ion Batteries with a Long-Term Cycling Stability
ACS Sustainable Chemistry & Engineering ( IF 8.4 ) Pub Date : 2018-03-15 00:00:00 , DOI: 10.1021/acssuschemeng.7b03694
Jianbiao Wang 1, 2 , Lin Chen 1, 2 , Lingxing Zeng 3 , Qiaohua Wei 2 , Mingdeng Wei 1, 2
Affiliation  

Transition metal dichalcogenides (TMDs) have received intensive interests in lithium-ion batteries owing to their unique lithium-ion storage ability when evaluated as anode materials. In the present work, a nanocomposite of WSe2/CMK-5 was successfully fabricated via a nanocasting route, introducing the unique structure of mesoporous carbon (CMK-5) as a nanorecator. Benefiting from a synergetic effect of WSe2 nanosheets and mesoporous carbon, the WSe2/CMK-5 hybrid electrode exhibited large reversible capacity, high rate performance, and excellent long-term cycling stability. For instance, a specific capacity of 490 mA h g–1 can remain even after 600 cycles at a current density of 0.5 A g–1.

中文翻译:

WSe 2 / CMK-5纳米复合材料的原位合成可充电锂离子电池,具有长期循环稳定性

过渡金属二卤化物(TMD)由于在评估为负极材料时具有独特的锂离子存储能力,因此在锂离子电池中引起了广泛关注。在目前的工作中,通过纳米浇铸路线成功制造了WSe 2 / CMK-5纳米复合材料,并引入了介孔碳(CMK-5)的独特结构作为纳米还原剂。受益于WSe 2纳米片和中孔碳的协同作用,WSe 2 / CMK-5杂化电极具有大的可逆容量,高倍率性能和出色的长期循环稳定性。例如,即使在电流密度为0.5 A g –1的情况下经过600次循环,也可以保持490 mA hg –1的比容量。
更新日期:2018-03-15
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