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In situ fabrication of silver-based nanostructures using electron beam†
CrystEngComm ( IF 3.1 ) Pub Date : 2018-03-21 00:00:00 , DOI: 10.1039/c7ce02244a
Cuncheng Ma 1, 2, 3, 4 , Xiangru Chen 1, 2, 3, 4 , Xiaohua Tan 1, 2, 3, 4 , Pengfei Hu 1, 2, 3, 4 , Qiang Li 1, 2, 3, 4 , Yali Cao 4, 5, 6, 7 , Xue Liang 1, 2, 3, 4
Affiliation  

Herein, electron beam irradiation (EBI) was employed to in situ construct Ag-based micro/nanostructures. The composition of AgX@Ag (X = Cl, Br, etc.) composites and the size/morphology of silver nanoparticles (Ag-NPs) were tuned by adjusting the electron beam current density (EBCD) and the feeding dose of electrons. A hypothesis of gas–solid fluid-bed composed of atomic gas and nanocrystals is suggested to discuss the nanoparticle constructions with EBI. The low/medium EBCD creates a fixed fluid-bed for AgX@Ag-NPs and piled-pore architecture of Ag-NPs (PPAAg-NPs), while a high EBCD sets up a stirred fluid-bed for monodispersed Ag-NPs. Hopefully, this strategy would promote nanotechnology.

中文翻译:

利用电子束原位制备银基纳米结构

在本文中,电子束照射(EBI)用于原位构建基于Ag的微/纳米结构。卤化银的组合物@的Ag(X =氯- ,溴- )复合材料和银纳米颗粒的尺寸/形态(银纳米颗粒)通过调节所述电子束电流密度(EBCD)和电子的输送剂量调谐。提出了一种由原子气体和纳米晶体组成的气固流化床的假说来讨论EBI的纳米颗粒结构。低/中级EBCD为AgX @ Ag-NPs和Ag-NPs(PPA Ag-NPs)的堆积孔结构创建了固定的流化床,而高EBCD为单分散的Ag-NPs设置了搅拌的流化床。希望这一战略将促进纳米技术的发展。
更新日期:2018-03-21
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