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Cross impact of CO2 phase and impurities on the corrosion behavior for stainless steel and carbon steel in water-containing dense CO2 environments
International Journal of Greenhouse Gas Control ( IF 3.9 ) Pub Date : 2018-03-19 , DOI: 10.1016/j.ijggc.2018.02.011
Minghe Xu , Qian Zhang , Zhe Wang , Jianmin Liu , Zheng Li

A series of study was conducted to investigate the corrosion behavior of 2Cr13 stainless steel and X65 carbon steel exposed to water-saturated and water-unsaturated dense CO2 environments with SO2 and O2 impurities in the conditions of 25 °C and 50 °C, 8 MPa. Each test lasted for 48 h. The cross impacts of CO2 phase (liquid phase and supercritical phase), water contents and steel types on the corrosion behavior were elaborately discussed. In water-saturated impure dense CO2 with SO2, SO2/O2 systems, the impacts of single impurity of SO2 and multiple impurities of SO2 and O2 on accelerating general corrosion for both 2Cr13 and X65 steels was much stronger in the supercritical CO2 system than in the liquid CO2 system. At water-unsaturated conditions, 2Cr13 stainless steel exhibited better resistance to the general corrosion attack in liquid and supercritical CO2 with SO2 in comparison with X65 carbon steel, but suffered high risk of localized corrosion in liquid CO2 mixtures. The 2Cr13 and X65 steels could bear higher amounts of water in supercritical CO2 with SO2 systems (∼1300 ppm H2O) than in the liquid CO2 with SO2 systems (<300 ppm H2O).



中文翻译:

CO 2相和杂质对含水致密CO 2环境中不锈钢和碳钢腐蚀行为的交叉影响

进行了一系列研究,以研究2Cr13不锈钢和X65碳钢在25°C和50°C条件下暴露于水饱和和水不饱和致密CO 2环境中的SO 2和O 2杂质的腐蚀行为。,8兆帕。每次测试持续48小时。详细讨论了CO 2相(液相和超临界相),水含量和钢种对腐蚀行为的交叉影响。在水饱和的不纯的致密CO 2与SO 2,SO 2 / O 2个系统,SO的单杂质的影响2和SO的多个杂质2和O2对加速2Cr13和X65钢的全面腐蚀的影响在超临界CO 2系统中比在液态CO 2系统中强得多。在水不饱和条件下,与X65碳钢相比,2Cr13不锈钢在带有SO 2的液态和超临界CO 2中表现出更好的耐一般腐蚀性能,但在液态CO 2混合物中存在局部腐蚀的高风险。2Cr13和X65钢在超临界CO 2中使用SO 2体系(约1300 ppm H 2 O)比在液态CO 2中使用SO 2可以承载更多的水。系统(<300 ppm H 2 O)。

更新日期:2018-03-19
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