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Single and bimetallic catalyst screenings of noble metals for methane combustion
Catalysis Communications ( IF 3.7 ) Pub Date : 2018-03-20 , DOI: 10.1016/j.catcom.2018.03.022
Weerit Kumsung , Metta Chareonpanich , Paisan Kongkachuichay , Selim Senkan , Anusorn Seubsai

Single metals and bimetallics impregnated on γ-Al2O3 were screened for methane combustion. A screening of 20 noble metals was first performed in a fuel-rich condition, revealing the top six active metals: Rh, Ru, Pd, Pt, Cu, and Cr, in order of decreasing activity. Then, the screening of the combinations of these six metals delivered several catalysts that offered a higher methane conversion when compared to the most active single catalysts. (4 wt% Rh + 1 wt% Cr)/γ-Al2O3 achieved the highest methane combustion and provided excellent stability. NH3-TPD analysis revealed strong acid sites playing a key role in the activation of methane.



中文翻译:

用于甲烷燃烧的贵金属的单金属和双金属催化剂筛选

浸渍在γ-Al系金属单质和bimetallics 2 ö 3筛选甲烷燃烧。首先在富含燃料的条件下进行20种贵金属的筛选,以活性降低的顺序显示了前六种活性金属:Rh,Ru,Pd,Pt,Cu和Cr。然后,对这六种金属的组合进行了筛选,得到了几种催化剂,与活性最高的单一催化剂相比,甲烷的甲烷转化率更高。(4重量%的Rh + 1重量%的Cr)/γ-Al系2 ö 3实现的最高甲烷燃烧和提供极好的稳定性。NH 3 -TPD分析表明强酸位在甲烷活化中起关键作用。

更新日期:2018-03-20
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