Hydrophosphorylated fullerene derivatives were readily prepared in one step by treating C 60 with Ph 3 – n PCl n ( n = 1–3) and ROH (R = H, alkyl). The one-pot reaction could be performed under mild conditions with moderate to good yields. Dichlorophenylphosphine and alcohols exhibited unexpected reactivity towards C 60 . A possible reaction mechanism involving the formation of P(III)–OH in situ was proposed to explain the experimental results.

中文翻译：

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从 C60 和 Ph3–n PCl n /ROH 形成氢磷酸化富勒烯的一锅法反应

通过用Ph 3 – n PCl n (n = 1–3) 和ROH (R = H，烷基) 处理C 60 ，很容易一步制备氢磷酸化富勒烯衍生物。一锅反应可以在温和的条件下进行，产率中等至良好。二氯苯基膦和醇对C 60 表现出出乎意料的反应性。提出了一种可能的反应机制，包括原位形成 P(III)-OH，以解释实验结果。