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Benzimidazolium Naphthoxide Betaine Is a Visible Light Promoted Organic Photoredox Catalyst
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2018-03-14 00:00:00 , DOI: 10.1021/acs.joc.8b00282
Eietsu Hasegawa 1 , Norihiro Izumiya 1 , Tomoaki Miura 1 , Tadaaki Ikoma 1, 2 , Hajime Iwamoto 1 , Shin-ya Takizawa 3 , Shigeru Murata 3
Affiliation  

Benzimidazolium naphthoxide (ONap-BI+) was first synthesized and utilized as an unprecedented betaine photoredox catalyst. Photoexcited state of ONap-BI+ generated by visible light irradiation catalyzes the reductive deiodination as well as desulfonylation reactions in which 1,3-dimethyl-2-phenylbenzimidazoline (Ph-BIH) cooperates with as an electron and hydrogen atom donor. Significant solvent effects on the reaction progress were discovered, and specific solvation toward imidazolium and naphthoxide moieties of ONap-BI+ was proposed.

中文翻译:

苯并咪唑萘酚甜菜碱是可见光促进的有机光氧化还原催化剂

苯并咪唑和萘酚(- ONap-BI +)首先合成并作为一个前所未有的甜菜碱photoredox催化剂利用。可见光辐射产生的 ONap-BI +的光激发态催化还原性碘化反应以及1,3-二甲基-2-苯基苯并咪唑啉(Ph-BIH)作为电子和氢原子供体协同作用的脱磺酰基反应。对反应进展显著溶剂效应被发现,并且朝向的咪唑和萘酚结构部分特定溶剂化- ONap-BI +提出。
更新日期:2018-03-14
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