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Sodium borohydride and propylene glycol, an effective combination for the generation of 2.3 wt% of hydrogen
International Journal of Hydrogen Energy ( IF 7.2 ) Pub Date : 2018-03-19 , DOI: 10.1016/j.ijhydene.2018.02.169
Hanane Ould-Amara , Damien Alligier , Eddy Petit , Pascal G. Yot , Umit B. Demirci

Sodium borohydride NaBH4 (SB) readily and completely reacts with four equivalents of propylene glycol HOCH2CH(OH)CH3 (PG), resulting in the liberation of four equivalents of H2 at temperatures starting from 25 °C. Alcoholysis (or glycolysis) takes place. The system SB-4PG is then an attractive H2 generator thanks to an effective gravimetric hydrogen storage capacity of 2.3 wt%. It offers several other advantages: there is no need of catalyst; there is no precipitation of by-product; PG is among the safest alcohols (much safer than e.g. methanol). The potential of SB-4PG as H2 generator is thus illustrated and discussed herein.



中文翻译:

硼氢化钠和丙二醇,是产生2.3 wt%氢的有效组合

硼氢化钠NaBH 4(SB)容易与四当量的丙二醇HOCH 2 CH(OH)CH 3(PG)完全反应,导致从25°C开始释放四当量的H 2。发生醇解(或糖酵解)。SB-4PG系统是有效的H 2发生器,这要归功于其有效的重量储氢能力为2.3 wt%。它还具有其他优点:不需要催化剂;没有副产物沉淀;PG是最安全的醇类(除了安全得多中例如甲醇)。因此,本文示出并讨论了SB-4PG作为H 2发生器的潜力。

更新日期:2018-03-19
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