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Fabrication and characterization of highly transparent Y2O3 ceramics by hybrid sintering: A combination of hot pressing and a subsequent HIP treatment
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2018-03-18 , DOI: 10.1016/j.jeurceramsoc.2018.03.022
Lin-Lin Zhu , Young-Jo Park , Lin Gan , Ha-Neul Kim , Jae-Woong Ko , Hai-Doo Kim

We succeeded in the optimization of highly transparent Y2O3 ceramics with a submicrometer grain size approximately 0.6 μm by hot pressing (1300–1550 °C) and a subsequent HIP (1450 °C) treatment using commercial Y2O3 powders as starting powders and ZrO2 as a sintering additive. The optimum microstructure for the HIP treatment was prepared by hot pressing at a temperature as low as 1400 °C for 3 h with a relative density of 99.3%. The thus HIP-treated specimen showed the best transmittance (2 mm thick) ever reported of 83.4% and 78.3% at 1100 and 400 nm, respectively. Specifically, the transmittance using this hybrid sintering method improved substantially in the visible range compared to that of the counterpart using hot pressing only. A simulation of the transmittance based on the Beer-Lambert law and Mie scattering theory has proved that this improvement is mainly due to the elimination of nanopores below 15 nm in size.



中文翻译:

通过混合烧结制备和表征高度透明的Y 2 O 3陶瓷:热压和随后的HIP处理的组合

我们成功地通过热压(1300-1550°C)和随后的HIP(1450°C)处理,以商业Y 2 O 3粉末为起始原料,优化了亚微米级晶粒尺寸约为0.6μm的高透明Y 2 O 3陶瓷。粉末和ZrO 2作为烧结添加剂。通过在低至1400°C的温度下热压3 h(相对密度为99.3%)来制备用于HIP处理的最佳微观结构。这样进行HIP处理的样品在1100和400 nm处显示出最佳的透射率(2毫米厚),分别为83.4%和78.3%。具体地,与仅使用热压的对应物相比,使用这种混合烧结法的透射率在可见光范围内显着提高。根据比尔-兰伯特定律和米氏散射理论对透射率进行的仿真证明,这种改进主要是由于消除了尺寸小于15 nm的纳米孔。

更新日期:2018-03-18
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