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Control of solution and solid-state emission with conjugated polymers based on the boron pyridinoiminate structure by ring fusion
Polymer ( IF 4.6 ) Pub Date : 2018-03-19
Madoka Yamaguchi, Kazuo Tanaka, Yoshiki Chujo

The two types of conjugated polymers were synthesized with boron pyridinoiminate with or without the fused structure in the ligand moiety. From optical measurements, it was shown that the polymer involving the fused complex had intense luminescent property only in the solution state. In contrast, another polymer presented similar emission intensities both in the solution and film states. By introducing the simple ring fuse structure, solution and solid-state luminescent properties of conjugated polymer can be tuned. Finally, the aggregation-caused quenching-resistant luminescent polymer can be produced.



中文翻译:

基于吡啶吡啶亚硼化硼结构的共轭聚合物环熔控制溶液和固态发射

合成了两种类型的共轭聚合物,其中吡啶基亚氨基硼酸在配体部分中具有或不具有稠合结构。从光学测量结果表明,涉及熔融配合物的聚合物仅在溶液状态下才具有强烈的发光性能。相反,另一种聚合物在溶液态和膜态下都表现出相似的发射强度。通过引入简单的环形熔丝结构,可以调整共轭聚合物的溶液和固态发光性能。最终,可以产生由聚集引起的耐猝灭性发光聚合物。

更新日期:2018-03-19
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