This short review describes the history of scientific development of layer-by-layer assembly of charged polymers. Early studies of 1960s and 1970s include binding and complex formation of oppositely charged polymers and colloids. The subsequent studies in 1980s showed that stable molecular assemblies such as monolayer at the air–water interface and aqueous bilayer membrane were useful as partners of polyion complexation. Charge reversal due to excessive adsorption on the charged surface was established by surface forces measurement in early 1990s. Decher and Hong published their epoch-making paper in 1992.

中文翻译：

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溶液，界面和表面上的聚离子络合：逐层组装的传统

这篇简短的评论描述了带电聚合物逐层组装的科学发展历史。1960年代和1970年代的早期研究包括带相反电荷的聚合物和胶体的结合和复合物的形成。随后在1980年代的研究表明，稳定的分子组装体（如空气-水界面处的单分子层和水性双层膜）可作为聚离子络合的伙伴。通过在1990年代初期对表面力进行测量，可以确定由于在带电表面上过度吸附而导致的电荷反转。Decher和Hong在1992年发表了划时代的论文。