Abstract Microporous materials with higher uptake – offtake difference per adsorption – desorption cycle have great potential to design adsorption assisted chillers, heat pumps and thermal batteries. In this context, we report a green reaction method for synthesizing aluminium fumarate (AlFum) metal-organic framework (MOF). The water uptake on AlFum shows S-shape isotherm curve with sharp increase in uptake – offtake difference in a narrow pressure range. The proposed green synthesized AlFum exhibits higher deliverable energy capacity as compared to that of conventional (dimethylformamide based synthesis) AlFum for adsorptive cooling applications.

中文翻译：

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用于热转化应用的富马酸铝金属-有机骨架的绿色合成和表征

摘要 每次吸附-解吸循环具有更高吸收-吸收差异的微孔材料在设计吸附辅助冷却器、热泵和热电池方面具有巨大的潜力。在此背景下，我们报告了一种合成富马酸铝 (AlFum) 金属有机骨架 (MOF) 的绿色反应方法。AlFum 上的吸水量显示 S 形等温线，在狭窄的压力范围内吸水-吸水差异急剧增加。与用于吸附冷却应用的传统（基于二甲基甲酰胺的合成）AlFum 相比，所提出的绿色合成 AlFum 具有更高的可输送能量容量。