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Co-sensitization of Ruthenium(II) Dye-Sensitized Solar Cells by Coumarin based dyes
Chemical Physics Letters ( IF 2.8 ) Pub Date : 2018-03-17 , DOI: 10.1016/j.cplett.2018.03.033
Anish Babu Athanas , Shankar Thangaraj , Swarnalatha Kalaiyar

Co-sensitization technique has been appraised for attaining enhanced performance in dye-sensitized solar cells (DSSCs). DSSCs are fabricated with a heteroleptic Ru(II) sensitizer (RDAB1) containing 4,4’-diamino-2,2’-bipyridine (dabpy) ligand, co-sensitized with electron donor-acceptor type coumarin containing thiophene (CT) and indole (CI) moieties. The individual overall power conversion efficiency of the sensitizer is 5.44 %. Enhanced power conversion efficiencies of 6.34 % and 7.09 % were observed when RDAB1 was co-sensitized with Coumarin containing CI and CT respectively. The enhanced PCE can be attributed to the presence of co-sensitizers which effectively overcome the light absorption by I-/I3-, dye aggregation and charge recombination.



中文翻译:

香豆素基染料对钌(II)染料敏化太阳能电池的共敏化

共敏化技术已得到评估,可以在染料敏化太阳能电池(DSSC)中获得增强的性能。DSSC由含有4,4'-二氨基-2,2'-联吡啶(dabpy)配体的杂合Ru(II)敏化剂(RDAB1)制成,并与含有噻吩(CT)和吲哚的电子供体-受体香豆素共敏化。 (CI)部分。敏化剂的单个总功率转换效率为5.44%。当RDAB1与含CI和CT的香豆素共敏化时,观察到功率转换效率提高了6.34%和7.09%。增强的PCE可以归因于共敏化剂的存在下,通过I,其有效地克服了光吸收- / I 3 - ,染料聚集和电荷复合。

更新日期:2018-03-18
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