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A noble-metal-free SCR-LNT coupled catalytic system used for high-concentration NOx reduction under lean-burn condition
Catalysis Today ( IF 5.3 ) Pub Date : 2018-03-15 , DOI: 10.1016/j.cattod.2018.03.022
Rui You , Ming Meng , Jing Zhang , Lirong Zheng , Tiandou Hu , Xingang Li

A dual-bed fixed-bed reactor consisting of a selective catalytic reduction (SCR) catalyst and a lean NOx trap (LNT) catalyst is designed and employed for high-concentration NOx removal under lean-burn condition. The lean NOx could be partially reduced over the upstream SCR catalyst (Cu/Al2O3) by C3H6 in the stream, greatly increasing the efficiencies of both NOx storage and NOx reduction over the downstream LNT catalyst (La0.7Sr0.3CoO3). The activity tests for individual catalyst show that the Cu/Al2O3 containing 5 wt.% Cu is the optimal SCR catalyst, which exhibits similar temperature window of activity (300–350 °C) as the LNT catalyst La0.7Sr0.3CoO3. The relative ratio of CuO nanoparticles to surface CuAl2O4 spinel on Cu/Al2O3 is rather important for NO-SCR due to the requirements of appropriate oxidation ability of SCR catalysts. As compared with the single SCR or LNT catalyst, the dual-bed SCR-LNT coupled system shows much lower NOx leak in both lean- and rich-burn periods, especially under the condition of high NOx concentration and high space velocity. Additionally, the NOx to N2O selectivity over this coupled system is as low as ∼4%, showing obvious advantage over conventional noble metals-based SCR and LNT catalysts.



中文翻译:

稀薄燃烧条件下用于高浓度NOx还原的无贵金属SCR-LNT耦合催化系统

设计了由选择性催化还原(SCR)催化剂和稀薄NOx捕集器(LNT)催化剂组成的双层固定床反应器,并将其用于稀薄燃烧条件下的高浓度NOx去除。流中的C 3 H 6可以使上游SCR催化剂(Cu / Al 2 O 3)上的贫NOx部分还原,大大提高了下游LNT催化剂(La 0.7 Sr 0.3)的NOx储存效率和NOx还原效率CoO 3)。单个催化剂的活性测试表明,Cu / Al 2 O 3包含5 wt。%Cu的是最佳的SCR催化剂,与LNT催化剂La 0.7 Sr 0.3 CoO 3表现出相似的温度范围(300-350°C)。由于SCR催化剂具有适当的氧化能力的要求,对于NO-SCR ,CuO纳米颗粒与Cu / Al 2 O 3表面上的CuAl 2 O 4尖晶石的相对比例非常重要。与单SCR或LNT催化剂相比,双床SCR-LNT耦合系统在稀燃和浓燃期间均显示出低得多的NOx泄漏,特别是在高NOx浓度和高空速的条件下。另外,NOx转化为N 2在该偶联体系上的O选择性低至约4%,显示出优于常规的基于贵金属的SCR和LNT催化剂的明显优势。

更新日期:2018-03-15
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