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Porous Cryo-Dried MXene for Efficient Capacitive Deionization
Joule ( IF 39.8 ) Pub Date : 2018-03-14 , DOI: 10.1016/j.joule.2018.02.018
Weizhai Bao , Xiao Tang , Xin Guo , Sinho Choi , Chengyin Wang , Yury Gogotsi , Guoxiu Wang

Aerogel-like, porous Ti3C2Tx MXene architecture electrode displayed a high electroadsorption capacity for capacitive deionization of saline water. A vacuum freeze-drying process was employed to prevent the restacking of MXene nanosheets due to van der Waals forces, leading to the formation of a porous structure with a large specific surface area. When applied as electrode materials for capacitive deionization, porous MXene demonstrated a high specific capacitance of 156 F/g and a volumetric capacitance of 410 F/cm3 in 1 M sodium chloride (NaCl) electrolyte. The porous Ti3C2Tx MXene electrodes can deliver a high electroadsorption capacity of 118 mg/cm3 (45 mg/g) in 10,000 mg/L NaCl solution (applied voltage: 1.2 V) and excellent cycling stability (up to 60 cycles) in comparison with the restacked MXene and activated carbon electrodes, indicating its promising potential for desalination applications.



中文翻译:

多孔低温干燥的MXene可实现高效电容去离子

气凝胶状的多孔Ti 3 C 2 T x MXene结构电极对盐水的电容去离子具有很高的电吸附能力。为了防止由于范德华力导致的MXene纳米片的再堆叠,采用了真空冷冻干燥工艺,从而导致形成了具有大比表面积的多孔结构。当用作电容去离子电极材料时,多孔MXene在1 M氯化钠(NaCl)电解质中显示出156 F / g的高比电容和410 F / cm 3的体积电容。Ti 3 C 2 T x MXene多孔电极可提供118 mg / cm的高电吸附能力与重新堆叠的MXene和活性炭电极相比,在10,000 mg / L NaCl溶液(施加电压:1.2 V)中具有3(45 mg / g)和优异的循环稳定性(最多60个循环),表明其在海水淡化应用中具有广阔的前景。

更新日期:2018-03-14
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