Transition metal-catalyzed silylations have typically involved the use of homogeneous non-recyclable catalytic systems. In this work, the first example of a recyclable catalytic system for the synthesis of arylsilanes has been reported, which utilizes the bimetallic complex, Pd–Pt–Fe₃O₄ nanoparticles. Various arylsilanes were prepared by the reaction of aryl iodides (or bromides) with hydrosilanes. This methodology showed good functional group tolerance toward ester, ketone, aldehyde, nitro, and cyano groups. The bimetallic Pd–Pt–Fe₃O₄ catalytic system showed better activity than monometallic Pt–Fe₃O₄ and Pd–Fe₃O₄ catalysts. In addition, the bimetallic Pd–Pt–Fe₃O₄ catalytic system could be easily recovered and reused for over twenty cycles.

中文翻译：

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使用可磁循环使用的双金属Pd–Pt–Fe ₃ O ₄催化剂对卤代芳基进行芳基硅烷化†

过渡金属催化的甲硅烷基化通常涉及均相不可回收的催化体系的使用。在这项工作中，已经报道了合成芳基硅烷的可回收催化体系的第一个实例，该体系利用了双金属配合物Pd–Pt–Fe ₃ O ₄纳米颗粒。通过使芳基碘化物（或溴化物）与氢化硅烷反应来制备各种芳基硅烷。该方法显示出对酯，酮，醛，硝基和氰基的良好官能团耐受性。双金属Pd–Pt–Fe ₃ O ₄催化体系的活性优于单金属Pt–Fe ₃ O ₄和Pd–Fe ₃ O _4。催化剂。此外，双金属Pd–Pt–Fe ₃ O ₄催化体系可以轻松回收并重复使用超过20个循环。