Nickel(ii) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction†,Chemical Communications

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Nickel(ii) pincer complexes demonstrate that the remote substituent controls catalytic carbon dioxide reduction†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-03-13 00:00:00 , DOI: 10.1039/c7cc09507d
Dalton B. Burks _{1,

2,

3,

4} , Shakeyia Davis _{4,

5,

6,

7,

8} , Robert W. Lamb _{4,

9,

10,

11} , Xuan Liu _{4,

6,

12,

13} , Roberta R. Rodrigues _{4,

5,

6,

7,

8} , Nalaka P. Liyanage _{4,

5,

6,

7,

8} , Yujie Sun _{4,

6,

12,

13} , Charles Edwin Webster _{4,

9,

10,

11} , Jared H. Delcamp _{4,

5,

6,

7,

8} , Elizabeth T. Papish _{1,

2,

3,

4}

Affiliation

The first example of a CNC pincer ligand with a central pyridinol ligand is reported in a nickel(II) complex. This metal complex can be protonated or deprotonated reversibly in situ to switch on or off the photocatalytic performance towards CO₂ reduction. The O⁻ substituent appears essential for catalysis.

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