Glycidyl triazolyl polymer (GTP), which is the product of the Huisgen dipolar cycloaddition reaction between glycidyl azide polymer and alkyne derivatives, is featured here. GTP is the multifunctionalized poly(ethylene glycol) (PEG). The drawback of PEG is that linear PEG has the functional group only at both ends. The low loading capability of the functional groups limits the possibilities of PEG applications. GTP facilitates the synthesis of multifunctionalized PEG derivatives. In this article, 74 examples of GTP homopolymers and copolymers are introduced. The synthetic protocols and work‐up processes of GTP are summarized. In addition, application studies are reviewed: for example, stimuli‐responsive and self‐healing materials, materials for electrical memory devices, ion‐conductive materials, and biomedical materials. Finally, some issues on GTP synthesis and future directions for GTP‐based polymer materials are proposed.

中文翻译：

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缩水甘油基三唑基聚合物：叠氮化物-炔烃环加成反应官能化的聚乙二醇衍生物

缩水甘油基三唑基聚合物（GTP）是缩水甘油基叠氮化物聚合物与炔烃衍生物之间的惠斯根偶极环加成反应的产物。GTP是多功能的聚乙二醇（PEG）。PEG的缺点是线性PEG仅在两端具有官能团。官能团的低负载能力限制了PEG应用的可能性。GTP促进了多功能PEG衍生物的合成。本文介绍了GTP均聚物和共聚物的74个实例。总结了GTP的综合协议和处理过程。此外，还审查了应用研究：例如，刺激响应和自我修复材料，电存储设备材料，离子导电材料和生物医学材料。最后，