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A porous triptycene-based covalent polymer stabilized binary metal sulfide for enhanced hydrogen evolution under visible light†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-03-09 00:00:00 , DOI: 10.1039/c8cc00665b
Qian Liang 1, 2, 3, 4 , Sainan Cui 1, 2, 3, 4 , Song Xu 1, 2, 3, 4 , Chao Yao 1, 2, 3, 4 , Mark J. MacLachlan 5, 6, 7, 8 , Zhongyu Li 1, 2, 3, 4
Affiliation  

A novel triptycene-based covalent polymer (TCP) with a high surface area was constructed through the Suzuki coupling reaction. A very high photocatalytic H2 production rate of 50 670 μmol h−1 g−1 and superior photostability were achieved due to the intimate synergistic interactions between the TCP and Cd0.5Zn0.5S.

中文翻译:

多孔三茂铁基共价聚合物稳定的二元金属硫化物,可在可见光下增强氢的逸出

通过Suzuki偶联反应构建了一种新型的具有高表面积的基于三茂铁的共价聚合物(TCP)。由于TCP和Cd 0.5 Zn 0.5 S之间密切的协同相互作用,因此实现了非常高的光催化H 2生成速率50 670μmolh -1 g -1和优异的光稳定性。
更新日期:2018-03-09
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