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Multiple aromatic C–H bond activations by a dirhenium carbonyl complex†
Chemical Communications ( IF 4.9 ) Pub Date : 2018-03-08 00:00:00 , DOI: 10.1039/c7cc08556g
Richard D. Adams 1, 2, 3, 4 , Poonam Dhull 1, 2, 3, 4 , Jonathan D. Tedder 1, 2, 3, 4
Affiliation  

Multiple aromatic CH activations by a dirhenium complex have provided meta-related dimetallated arene rings in the complexes Re2(CO)8(μ-H)(μ-η2-1,2-μ-η2-3,4-C14H8)Re2(CO)8(μ-H), 3 and Re2(CO)8(μ-H)(μ-η1-1,μ-η1-3-C6H4)Re2(CO)8(μ-H), 4. Both products were characterized structurally by single crystal X-ray diffraction and DFT molecular orbital analyses.

中文翻译:

碳羰基络合物对多个芳香族碳氢键的活化作用

通过络合物的dirhenium多个芳香CH激活所提供的元-相关的复合物dimetallated芳烃环重新2(CO)8(μ-H)(μ-η 2 -1,2-μ-η 2 -3,4--C 14 ħ 8)重新2(CO)8(μ-H),3和R e 2(CO)8(μ-H)(μ-η 1 -1,μ-η 1 -3-C 6 H ^ 4)重新2(CO)8(μ-H),4。两种产物的结构均通过单晶X射线衍射和DFT分子轨道分析进行表征。
更新日期:2018-03-08
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