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Silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols with PhSO2SCF2H or PhSO2SCF3†
Organic Chemistry Frontiers ( IF 5.4 ) Pub Date : 2018-03-06 00:00:00 , DOI: 10.1039/c8qo00115d
Bin Xu 1, 2, 3, 4 , Decai Wang 1, 2, 3, 4 , Yonghong Hu 1, 2, 3, 4 , Qilong Shen 5, 6, 7, 8, 9
Affiliation  

A silver-catalyzed ring-opening difluoromethylthiolation/trifluoromethylthiolation of cycloalkanols including cyclopropanols, cyclobutanols, cyclopentanols, cyclohexanols and cycloheptanols was described. A variety of common functional groups such as fluoride, chloride, bromide, iodide, trifluoromethyl, cyano and ester groups were compatible.

中文翻译:

银-催化的开环difluoromethylthiolation /与PhSO环烷醇的trifluoromethylthiolation 2 SCF 2 H或PhSO 2 SCF 3

描述了银催化的包括环丙醇,环丁醇,环戊醇,环己醇和环庚醇的环烷醇的开环二氟甲基硫醇化/三氟甲基硫醇化。多种常见的官能团如氟,氯,溴,碘,三氟甲基,氰基和酯基是相容的。
更新日期:2018-03-06
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