Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis†,Organic Chemistry Frontiers

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Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis†
Organic Chemistry Frontiers ( IF 5.4 ) Pub Date : 2018-03-06 00:00:00 , DOI: 10.1039/c8qo00082d
Xiao-Yang Pan _{1,

2,

3,

4,

5} , Yue Zhao _{1,

2,

3,

4,

5} , Hong-An Qu _{4,

6,

7} , Jin-Hong Lin _{5,

8,

9,

10,

11} , Xiao-Chun Hang _{1,

2,

3,

4} , Ji-Chang Xiao _{5,

8,

9,

10,

11}

Affiliation

The tri- and di-fluoroethylation of alkenes with sulfonium salts, (Ph₂S⁺CH₂R_F TfO⁻) (R_F = CF₃ or HCF₂), by visible light photoredox catalysis to give tri-/di-fluoroethyl alkenes or methoxytri-/di-fluoroethylation products are described. It was found that varying the reaction solvent led to changes in the reaction path.

中文翻译：

可见光光氧化还原催化烯烃的三氟乙基和二氟乙基化†

通过可见光氧化还原催化，用with盐（Ph ₂ S ⁺ CH ₂ R _F TfO ^-）（R _F = CF ₃或HCF ₂）进行烯烃的三氟和二氟乙基化，得到三氟/二氟乙基烯烃或描述了甲氧基三-/二氟乙基化产物。发现改变反应溶剂导致反应路径的改变。

更新日期：2018-03-06

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