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Synthesis of Nitroolefins and Nitroarenes under Mild Conditions
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2018-03-05 00:00:00 , DOI: 10.1021/acs.joc.7b03289
Mahmoud Zarei 1 , Ehsan Noroozizadeh 1 , Ahmad R. Moosavi-Zare 2 , Mohammad A. Zolfigol 1
Affiliation  

1,3-Disulfonic acid imidazolium nitrate {[Dsim]NO3} was prepared and characterized as a new ionic liquid and nitrating agent for the ipso-nitration of various arylboronic acids and nitro-Hunsdiecker reaction of different α,β-unsaturated acids and benzoic acid derivatives, by in situ generation of NO2 to give various nitroarenes and nitroolefins without using any cocatalysts and solvents under mild conditions.

中文翻译:

温和条件下硝基烯烃和硝基芳烃的合成

制备了1,3-二磺酸硝酸咪唑鎓{[Dsim] NO 3 },并将其表征为新型离子液体和硝化剂,用于各种芳基硼酸的ipso-硝化以及不同的α,β-不饱和酸和苯甲酸衍生物,在温和条件下不使用任何助催化剂和溶剂,通过原位生成NO 2生成各种硝基芳烃和硝基烯烃。
更新日期:2018-03-05
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