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Heterobimetallic Lanthanide–Sodium Alkoxides Catalyze the Amidation of Esters
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2018-03-02 , DOI: 10.1002/ajoc.201800070 Zhao Li 1 , Chao Wang 1 , Yaorong Wang 1 , Dan Yuan 1 , Yingming Yao 1
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2018-03-02 , DOI: 10.1002/ajoc.201800070 Zhao Li 1 , Chao Wang 1 , Yaorong Wang 1 , Dan Yuan 1 , Yingming Yao 1
Affiliation
Heterobimetallic lanthanide–sodium alkoxides Ln2Na8(OCH2CF3)14(THF)6 catalyzed the reaction of esters and amines to produce amides in up to 99 % yields. They showed high catalytic activity for a wide scope of substrates under solvent‐free conditions. The cooperation of lanthanum and sodium alkoxide is proposed to account for the good activity.
中文翻译:
异双金属镧系元素-醇钠催化酯的酰胺化
异双金属镧系元素-醇钠Ln 2 Na 8(OCH 2 CF 3)14(THF)6催化酯和胺的反应,以高达99%的产率生产酰胺。在无溶剂条件下,它们对多种底物均显示出高催化活性。提出镧和醇钠的配合以说明良好的活性。
更新日期:2018-03-02
中文翻译:
异双金属镧系元素-醇钠催化酯的酰胺化
异双金属镧系元素-醇钠Ln 2 Na 8(OCH 2 CF 3)14(THF)6催化酯和胺的反应,以高达99%的产率生产酰胺。在无溶剂条件下,它们对多种底物均显示出高催化活性。提出镧和醇钠的配合以说明良好的活性。