Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols,Green Chemistry

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Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols
Green Chemistry ( IF 9.8 ) Pub Date : 2018-02-28 00:00:00 , DOI: 10.1039/c8gc00424b
Ashot V. Arzumanyan _{1,

2,

3,

4} , Irina K. Goncharova _{1,

2,

3,

4} , Roman A. Novikov _{2,

3,

4,

5} , Sergey A. Milenin _{2,

4,

6,

7} , Konstantin L. Boldyrev _{2,

4,

6,

7} , Pavel N. Solyev _{2,

3,

4,

5} , Yaroslav V. Tkachev _{2,

3,

4,

5} , Alexander D. Volodin _{1,

2,

3,

4} , Alexander F. Smol'yakov _{1,

2,

3,

4,

8} , Alexander A. Korlyukov _{1,

2,

3,

4,

9} , Aziz M. Muzafarov _{1,

2,

3,

4,

6}

Affiliation

A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)₂ or Cu(OAc)₂/NHPI-catalyzed oxidation of hydride siloxanes using “green”, commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic).

中文翻译：

需氧的Co或Cu / NHPI催化氢化硅氧烷的氧化：合成硅氧烷醇

提出了一种高效的制备方法，该方法基于需氧的Co（OAc）₂或Cu（OAc）₂ / NHPI催化的氢化硅氧烷的氧化，使用“绿色”，市售，简单廉价的试剂和温和的反应条件进行。这是合成具有各种结构（直链，支链和环状）的单，低聚和聚合硅氧烷醇的一般反应。

更新日期：2018-04-03

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