当前位置: X-MOL 学术Nat. Rev. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Molecular machines for catalysis
Nature Reviews Chemistry ( IF 36.3 ) Pub Date : 2018-02-28 , DOI: 10.1038/s41570-018-0117
Lucy van Dijk , Michael J. Tilby , Robert Szpera , Owen A. Smith , Holly A. P. Bunce , Stephen P. Fletcher

The past few decades have seen tremendous progress in the synthesis and operation of molecular systems capable of controlled mechanical movement. Here, we review the use of molecular machines as catalysts for controlling chemical reactions. We highlight the various catalyst designs with a focus on how mechanical motion is used to control catalysis with varying degrees of success. This Review discusses the current challenges of designing effective catalysts, the scope and limitations of various systems and the future potential and aims for the field. Although it is difficult to predict which concepts will become most important, as much of the work is at the proof-of-concept level, it seems clear that molecular machines have the potential to substantially impact the field of catalysis.



中文翻译:

分子催化机器

在过去的几十年中,在能够控制机械运动的分子系统的合成和操作中取得了巨大的进步。在这里,我们回顾了分子机器作为控制化学反应的催化剂的用途。我们重点介绍各种催化剂设计,重点是如何使用机械运动来控制催化并获得不同程度的成功。本综述讨论了设计有效催化剂的当前挑战,各种系统的范围和局限性以及未来的潜力,并针对该领域进行了探讨。尽管很难预测哪些概念将变得最重要,但由于许多工作仍处于概念验证的水平,因此似乎很明显,分子机器具有极大地影响催化领域的潜力。

更新日期:2018-02-28
down
wechat
bug