An overview is provided on the recent advances in transglycosylation of cellulose and hemicellulose with either short‐chain or long‐chain alkyl alcohols. Catalytic processes are compared in terms of yield, selectivity and space‐time yield, with a view to identifying the most promising pathways for future developments. In this context, the synthesis of alkylpolyglycosides directly from lignocellulosic biomass is discussed while keeping in mind the impact of the botanical origin on the transglycosylation reaction and the product distribution. A section dedicated to the physicochemical properties and ecological footprint of alkylpolyglycosides is also included.

中文翻译：

---

转糖基化：从木质纤维素生物质中获取烷基多糖苷的关键反应

本文概述了使用短链或长链烷基醇对纤维素和半纤维素进行糖基转移的最新进展。比较了催化过程的产率，选择性和时空产率，以期确定未来发展的最有希望的途径。在本文中，讨论了直接从木质纤维素生物质合成烷基多糖苷的方法，同时牢记植物来源对转糖基化反应和产物分布的影响。还包括专门介绍烷基多糖苷的理化性质和生态足迹的部分。