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High-quality alignment of nematic liquid crystals using periodic nanostructures created by nonlinear laser lithography
Journal of Molecular Liquids ( IF 6 ) Pub Date : 2018-02-20 , DOI: 10.1016/j.molliq.2018.02.058
I.A. Pavlov , A.S. Rybak , A.M. Dobrovolskiy , V.M. Kadan , I.V. Blonskiy , Z.I. Kazantseva , I.A. Gvozdovskyy

It is well known that today two main and well studied methods for alignment of liquid crystals has been used, namely: rubbing and photoalignment technologies, that lead to the change of anisotropic properties of aligning layers and long-range interaction of the liquid crystal molecules in a mesophase. In this manuscript, we use the nonlinear laser lithography technique, which was recently presented as a fast, relatively low-cost method for a large area micro and nanogrooves fabrication based on laser-induced periodic surface structuring, as a new perspective method of the alignment of nematic liquid crystals. 920 nm periodic grooves were formed on a Ti layer processed by means of the nonlinear laser lithography and studied as an aligning layer. Aligning properties of the periodic structures of Ti layers were examined by using a combined twist LC cell. In addition, the layer of the nanostructured Ti was coated with an oxidianiline-polyimide film with annealing of the polymer film followed without any further processing. The dependence of the twist angle of LC cells on a scanning speed and power of laser beam during processing of the Ti layer was studied. The azimuthal anchoring energy of Ti layers with a periodic nanostructure was calculated. The maximum azimuthal anchoring energy for the nanostructured Ti layer was about 4.6 × 10−6 J/m2, which is comparable to the photoalignment technology. It was found that after the deposition of a polyimide film on the periodic nanostructured Ti layer, the gain effect of the azimuthal anchoring energy to ~1 × 10−4 J/m2 is observed. Also, AFM study of aligning surfaces was carried out.



中文翻译:

使用由非线性激光光刻技术产生的周期性纳米结构对向列液晶进行高质量取向

众所周知,今天已经使用了两种主要且经过充分研究的液晶取向方法,即:摩擦和光取向技术,其导致取向层的各向异性性质的改变以及液晶分子在液晶中的长程相互作用。中间相。在本文中,我们使用了非线性激光光刻技术,该技术最近作为基于激光诱导的周期性表面结构化的大面积微米和纳米沟槽制造的一种快速,相对低成本的方法,被用作对准的一种新的透视方法。向列液晶。在通过非线性激光光刻法处理的Ti层上形成920nm的周期性凹槽,并且将其作为取向层进行研究。Ti层的周期性结构的对准特性通过使用组合扭曲LC单元进行了检查。另外,在对聚合物膜进行退火之后,用氧化苯胺-聚酰亚胺膜涂覆纳米结构化的Ti层,然后不进行任何进一步的处理。研究了液晶盒扭曲角对钛层加工过程中扫描速度和激光束功率的依赖性。计算了具有周期性纳米结构的Ti层的方位锚固能。纳米结构Ti层的最大方位锚固能量约为4.6×10 研究了液晶盒扭曲角对钛层加工过程中扫描速度和激光束功率的依赖性。计算了具有周期性纳米结构的Ti层的方位锚固能。纳米结构Ti层的最大方位锚固能量约为4.6×10 研究了液晶盒扭曲角对钛层加工过程中扫描速度和激光束功率的依赖性。计算了具有周期性纳米结构的Ti层的方位锚固能。纳米结构Ti层的最大方位锚固能量约为4.6×10-6  J / m 2,可与光取向技术相比。发现在周期性纳米结构的Ti层上沉积聚酰亚胺膜之后,观察到方位锚固能量对〜1×10 -4  J / m 2的增益效应。此外,进行了AFM对准表面的研究。

更新日期:2018-02-20
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