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Surfactant-Assisted BaTiO3:Eu3+@SiO2 Core–Shell Superstructures Obtained by Ultrasonication Method: Dormant Fingerprint Visualization and Red Component of White Light-Emitting Diode Applications
ACS Sustainable Chemistry & Engineering ( IF 8.4 ) Pub Date : 2018-02-20 00:00:00 , DOI: 10.1021/acssuschemeng.7b04870
Dhanalakshmi Muniswamy 1, 2 , Hanumanthappa Nagabhushana 3 , R. B. Basavaraj 3 , Giriyapura Prabhukumar Darshan 4 , Daruka Prasad B 5
Affiliation  

Nanoparticles (NPs) synthesized via a facile sonochemical route showed excellent assembly of BaTiO3:Eu3+@SiO2 superstructures (SS) using CTAB as a surfactant. Crystallite size, phase, surface science, and core–shell confirmation were determined through advanced characterization techniques. Experimental parameters like pH, temperature, and surfactant concentration were varied and resulted in SS with high surface modifications, and the possible mechanisms for the same are reported. Scanning electron microscopy images revealed broomlike structures, and various experimental parameters resulting in them dissolving into freestanding sticks are discussed. CIE chromaticity coordinates were in the range of the orange-red to pure red. Drawbacks associated with the commercial powder dusting method for visualizing dormant fingerprint (DFP), namely, high background scattering and high autofluorescence of the substrate material, were improved with the help of the prepared SS as a dusting powder. Visualization of DFPs and sweat pores on various kinds of surfaces was studied effectively and systematically and revealed the well-defined first-, second-, and third-level ridge particulars with high contrast, high selectivity, and low background interference. These results suggest different strategies to engineer SS and highlights a method to obtain high-resolution DFPs. The prepared compounds are also utilized in antiforging ink and optoelectronics applications.

中文翻译:

表面活性剂辅助的BaTiO 3:Eu 3+ @SiO 2核壳超结构的超声方法:休眠指纹可视化和白色发光二极管应用中的红色成分

通过便捷的声化学途径合成的纳米颗粒(NPs)表现出BaTiO 3:Eu 3+ @SiO 2的出色组装CTAB作为表面活性剂的上层建筑(SS)。通过先进的表征技术确定了微晶的大小,相,表面科学和核壳结构。pH,温度和表面活性剂浓度等实验参数发生变化,导致SS具有较高的表面改性,并报道了可能的机制。扫描电子显微镜图像显示出扫帚状结构,并讨论了使它们溶解在独立式棍棒中的各种实验参数。CIE色度坐标在橙红色到纯红色的范围内。与用于可视化休眠指纹(DFP)的商业粉末喷粉方法相关的缺点,即底物材料的高背景散射和高自发荧光,借助制备的粉尘SS进行了改进。对DFPs和各种表面上的汗孔的可视化进行了有效而系统的研究,并揭示了清晰定义的第一,第二和第三级脊特征,具有高对比度,高选择性和低背景干扰。这些结果提出了设计SS的不同策略,并强调了一种获得高分辨率DFP的方法。制备的化合物还用于防伪油墨和光电应用。这些结果提出了设计SS的不同策略,并强调了一种获得高分辨率DFP的方法。制备的化合物还用于防伪油墨和光电应用。这些结果提出了设计SS的不同策略,并强调了一种获得高分辨率DFP的方法。制备的化合物还用于防伪油墨和光电应用。
更新日期:2018-02-20
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