Metal Organic Frameworks (MOFs) have been explored widely to create heterogeneity in a catalytic system. Catalytic applications require the use of stable catalysts with no leaching and easy recovery. In this regard, [email protected] is embedded in a poly-є-caprolactone (PCL) matrix by means of electrospinning to create a “catalytic carpet” which is highly efficient and can be recovered within seconds after catalysis. The obtained composite material is completely intact with a homogeneous distribution of the [email protected] throughout the electrospun PCL fiber matrix. The catalytic carpet was examined in the hydrogenation of cyclohexene and full conversion was obtained in just 90 min. Remarkably, a very large fraction (>65%) of the total Pt-atoms participate in the reaction. Reusability tests showed that the material could be recycled for at least 4 runs without detectable Cr and Pt leaching displaying the durability of the catalytic carpets. Complete recovery is achieved with zero weight loss while fully preserving the crystalline structure.

金属有机骨架（MOF）已被广泛研究以在催化体系中产生异质性。催化应用需要使用稳定的催化剂，且不得浸出且易于回收。在这方面，[电子邮件保护]通过静电纺丝嵌入聚ε-己内酯（PCL）基质中，以形成高效的“催化毯”，并且可以在催化后几秒钟内将其回收。所获得的复合材料是完整无缺的，在整个电纺PCL纤维基质中[受电子邮件保护]均匀分布。在环己烯的氢化过程中检查了催化毯，仅在90分钟内就获得了完全转化。值得注意的是，全部Pt原子中有很大一部分（> 65％）参与了反应。可重复使用性测试表明，该材料至少可循环使用4次，而没有可检测到的Cr和Pt浸出，显示了催化毯的耐用性。零重量损失实现了完全恢复，同时完全保留了晶体结构。