Expedient C−H additions of heteroarenes onto aldimines were realized by a sustainable manganese catalysis manifold within a removable directing group strategy. The C−H activation features most user‐friendly reaction conditions, excellent chemo‐ and position‐selectivity as well as ample substrate scope. Detailed experimental mechanistic studies suggest an organometallic C−H manganesation mode of action.

中文翻译：

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亚胺的可持续锰催化的CH活化/加氢芳基化

通过在可移动的导向组策略中实现可持续的锰催化流形，可以在杂草胺上方便地添加杂芳烃到CH上。C-H活化具有大多数用户友好的反应条件，出色的化学和位置选择性以及充足的底物范围。详细的实验机理研究表明有机金属CH锰的作用方式。