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Facile synthesis of ultra stable Fe3O4@Carbon core-shell nanoparticles entrapped satellite au catalysts with enhanced 4-nitrophenol reduction property
Journal of the Taiwan Institute of Chemical Engineers ( IF 5.7 ) Pub Date : 2018-02-13 , DOI: 10.1016/j.jtice.2018.01.026
Cheng Gong , Ziwei Zhou , Jian Li , Haijun Zhou , Rui Liu

In this work, we report a facile synthesis of Fe3O4@Carbon core-shell nanoparticles (NPs) entrapped satellite Au NPs (denoted as Fe3O4@[email protected]). First, multiple Au NPs are directly deposited within the resorcinol-formaldehyde layer of Fe3O4@RF in the absence of any external reducing agent. Fe3O4@[email protected] NPs obtained after direct carbonization of Fe3O4@[email protected] remain the well dispersion of Au NPs within the carbon layer, even after high temperature treatment at 700 °C. Fe3O4@[email protected] NPs exhibit ultra stability, high catalytic performance, easy separation and efficient reusability for the reduction of 4-nitrophenol (4-NP). The simple synthesis method of ultra stable Fe3O4@C encapsulated with catalytic Au NPs in this work provides a platform for the preparation of other functional nanocomposites.



中文翻译:

易于合成具有增强的4-硝基苯酚还原性能的超稳定Fe 3 O 4 @碳核壳纳米粒子截留的卫星金催化剂

在这项工作中,我们报告的简便合成的Fe 3 ö 4 @Carbon核-壳纳米颗粒(NP)中夹住卫星金纳米粒子(表示为铁3 ö 4 @ [电子邮件保护])。首先,在没有任何外部还原剂的情况下,多个Au NP直接沉积在Fe 3 O 4 @RF的间苯二酚-甲醛层中。将Fe 3 O 4直接碳化后获得的Fe 3 O 4 NPs,即使经过700°C高温处理后,仍能在碳层中良好地分散Au NPs。铁3 O 4@ [受电子邮件保护] NPs具有超强的稳定性,高催化性能,易于分离和有效的可重复使用性,可用于还原4-硝基苯酚(4-NP)。在这项工作中,用催化金纳米颗粒包裹的超稳定Fe 3 O 4 @C的简单合成方法为制备其他功能纳米复合材料提供了平台。

更新日期:2018-02-13
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