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Vapor-phase assisted hydrothermal carbon from sucrose and its application in acid catalysis
Green Chemistry ( IF 9.8 ) Pub Date : 2018-02-06 00:00:00 , DOI: 10.1039/c7gc02236k
R. Zhong 1, 2, 3, 4, 5 , Y. Liao 1, 2, 3, 4, 5 , R. Shu 6, 7, 8, 9, 10 , L. Ma 6, 7, 8, 9, 10 , B. F. Sels 1, 2, 3, 4, 5
Affiliation  

A novel and practical synthesis method for carbonaceous materials was proposed by the vapor-phase hydrothermal treatment of sucrose at a mild 200 °C temperature. The resultant carbon possesses a 52 m2 g−1 specific surface area and 0.18 cm3 g−1 total pore volume – values that are substantially higher than those of conventional hydrothermally treated sugar solutions. The functionalization of the porous carbon with –SO3H led to acidic materials with high catalytic activity and selectivity towards, e.g., the sylvan condensation with furfural.

中文翻译:

蔗糖汽相辅助热液碳及其在酸催化中的应用

提出了一种新颖实用的碳质材料合成方法,该方法是在200°C温和的条件下对蔗糖进行气相水热处理。所得碳具有52 m 2 g -1的比表面积和0.18 cm 3 g -1的总孔体积–值大大高于常规水热处理糖溶液的值。多孔碳用–SO 3 H的官能化导致酸性物质具有较高的催化活性和选择性,例如,与糠醛的席尔伐缩合反应。
更新日期:2018-03-20
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