The concept of green chemistry began in the USA in the 1990s. Since the publication of the 12 principles of this concept, many reactions in organic chemistry have been developed, and chemical products have been synthesized under environmentally friendly conditions. Lewis acid mediated synthetic transformations are by far the most numerous and best studied. However, the use of certain Lewis acids may cause risks to environmental and human health. This Review discusses the evolution of Lewis acid catalyzed reactions from a homogeneous liquid phase to the solid phase to yield the expected organic molecules under green, safe conditions. In particular, recent developments and applications of biosourced catalysts from plants are highlighted.

中文翻译：

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从传统的路易斯酸到多相蒙脱土K10：用作绿色路易斯酸的生态友好型植物基催化剂

绿色化学的概念始于1990年代的美国。自从该概念的12条原则发布以来，已经开发了有机化学中的许多反应，并且在环境友好的条件下合成了化学产品。迄今为止，路易斯酸介导的合成转化是数量最多，研究最好的。但是，某些路易斯酸的使用可能会对环境和人类健康造成风险。这篇综述讨论了路易斯酸催化反应从均相液相向固相演变的过程，以在绿色，安全的条件下产生预期的有机分子。特别地，强调了来自植物的生物来源催化剂的最新发展和应用。